N-(2-Chlorophenyl)succinimide
نویسندگان
چکیده
In the title compound, C(10)H(8)ClNO(2), the dihedral angle between the aromatic benzene ring and the imide segment is 69.5 (1)°. In the crystal structure, mol-ecules are linked by very weak C-H⋯π inter-actions along the [001] direction.
منابع مشابه
N-(3-Chlorophenyl)succinimide
In the title compound, C(10)H(8)ClNO(2), the chloro-benzene and the essentially planar (r.m.s. deviation = 0.030 Å) pyrrolidine ring are tilted by 59.5 (1)° with respect to one another.
متن کامل//2-Chlorokomplexe von Succinimid und N-Chlorsuccinimid. Die Kristallstrukturen von PPh4[Cl(Succinimid)2], PPh4[[CI(N-Cl-Succinimid)2] und N-Chlorphthalimid /<2-Chloro Complexes of Succinimide and N-Chlorosuccinimide. The Crystal Structures of PPh4[Cl(Succinimide)2], PPh4[Cl(N-Cl-Succinimide)2] and N-Chlorophthalimide
The donor-acceptor complexes PPh4[Cl(succinimide)2] and PPh4[Cl(N-chlorosuccinimide)2] have been prepared by reactions of PPh4Cl with succinimide and N-chlorosuccinimide, re spectively. in acetonitrile solutions. The complexes have been characterized by IR spectros copy and by crystal structure determinations. The crystal structure of N-chlorophthalimide has also been solved. N-chlorophthalim...
متن کامل2-Methyl-3-(5-methyl-2-thienyl)-5-phenylperhydropyrrolo[3,4-d]isoxazole-4,6-dione
In the mol-ecule of the title compound, C(17)H(16)N(2)O(3)S, the phenyl ring is oriented with respect to the thio-phene and succinimide rings at dihedral angles of 88.08 (3) and 57.81 (3)°, respectively; the dihedral angle between the thio-phene and succinimide rings is 35.69 (3)°. The isoxazole ring adopts an envelope conformation with the N atom at the flap position. In the crystal structure,...
متن کاملComputational modeling of the enolization in a direct mechanism of racemization of the aspartic acid residue.
The rapid racemization of aspartic acid (Asp) residues in peptides and proteins is due mainly to the succinimide intermediate. However, there should be another mechanism for Asp racemization without intermediacy of the succinimide. The direct H-atom abstraction from the C(alpha)-atom that leads to the enol form of the Asp residue is one possibility. In another study, we have computationally pre...
متن کامل4-Chloro-3-fluoro-2-methylaniline–pyrrolidine-2,5-dione (1/1)
Chlorination of 3-fluoro-2-methyl-aniline with N-chloro-succinimide gave one major regioisomer whose structure was determined by X-ray crystallography. The product was found to have cocrystallized with succinimide, giving the title compound, C(7)H(7)ClFN·C(4)H(5)NO(2). The crystal structure is stabilized by N-H⋯O hydrogen-bonding and π-π stacking inter-actions with a centroid-centroid distance ...
متن کامل